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Determination
of Polychlorinated Dibenzo-p-dioxins and Polychlorinated Dibenzofurans
from Municipal Waste Combustors – USEPA Method 23
USEPA Method 23 is used to determine emissions of polychlorinated
dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs)
from stationary sources. Other semivolatile organic compounds
(SVOCs) such as PAHs and PCBs may be determined using this method
with appropriate analytical modifications.
A sample is withdrawn isokinetically from the gas stream and collected
in a sample probe, on a glass fiber filter, and on a packed column
of adsorbent material (XAD-II resin). The PCDDs and PCDFs are
extracted from the sample, separated by high resolution gas chromatography
(HRGC), and measured by high resolution mass spectrometry (HRMS).
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